Institute of Chemistry of the Academy of Sciences of Moldova
Larisa Postolachi
chemjm_correspondence@yahoo.com
mEDRA
20161225
07
10.19261/cjm.2016.11(1).01
http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold201611(1)_10-20_Spataru.pdf
Institute of Chemistry of the Academy of Sciences of Moldova
mEDRA
01
Chemistry Journal of Moldova
05
ChemJMold
01
Institute of Chemistry of the Academy of Sciences of Moldova
MD
07
1857-1727
JB
07
2345-1688
JD
11
1
June 2016
01
201606
1
12
10
20
11
01
The Nature of the Co-C Bond Cleavage Processes in Methylcob(II)Alamin and Adenosylcob(III)Alamin
1
A01
Tudor Spataru
Spataru, Tudor
Tudor
Spataru
2
A01
Francisco Fernandez
Fernandez, Francisco
Francisco
Fernandez
01
eng
20
vitamin B12; mechanism; bio-catalysis; Pseudo-Jahn-Teller effect; DFT; MCSCF
01
No grounded mechanisms for Co-C vitamin B12 coenzyme bond breaking process and subsequent reactions have been found up to now. The influence of the mixing orbitals e.g. Pseudo-Jahn-Teller and similar effects on the reactions paths of bond-cleavage mechanisms of vitamin B12 co-factors must be taken into account. Afterward, the updated mechanisms of vitamin B12 bio-processes can be determined.
201606
2016
Institute of Chemistry of the Academy of Sciences of Moldova
10.1007/978-94-007-7500-8_9
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