Institute of Chemistry of the Academy of Sciences of Moldova Larisa Postolachi chemjm_correspondence@yahoo.com mEDRA 20161225

07 10.19261/cjm.2016.11(1).05 http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold201611(1)_39-49_Bulhac.pdf Institute of Chemistry of the Academy of Sciences of Moldova mEDRA 01 Institute of Chemistry of the Academy of Sciences of Moldova MD 07 1857-1727 JB 07 2345-1688 JD 11 1 June 2016 01 201606 5 11 39 49 11 1 A01 Ion Bulhac Bulhac, Ion Ion Bulhac 2 A01 Alexandra Deseatnic-Ciloci Deseatnic-Ciloci, Alexandra Alexandra Deseatnic-Ciloci 3 A01 Paulina Bourosh Bourosh, Paulina Paulina Bourosh 4 A01 Janetta Tiurina Tiurina, Janetta Janetta Tiurina 5 A01 Olga Bologa Bologa, Olga Olga Bologa 6 A01 Cezara Bivol Bivol, Cezara Cezara Bivol 7 A01 Steliana Clapco Clapco, Steliana Steliana Clapco 8 A01 Ana Verejan Verejan, Ana Ana Verejan 9 A01 Svetlana Labliuc Labliuc, Svetlana Svetlana Labliuc 10 A01 Olga Danilescu Danilescu, Olga Olga Danilescu 01 eng 20 iron complexes; nitrogen-containing ligands; structure; biological properties 01 Four coordination compounds of iron(III) with ligands based on hydrazine and sulfadiazine: FeCl3·digsemi·2H2O (I) (digsemi-semicarbazide diacetic acid dihydrazide, [Fe(HL)SO4] (II) (НL - sulfadiazine), [Fe(H2L1)(H2O)2](NO3)3·5H2O (III) (H2L1-2,6-diacetylpyridine bis(nicotinoylhydrazone) and [Fe(H2L2)(H2O)2](NO3)3•1.5H2O (IV) (H2L2 - 2,6-diacetylpyridine bis(isonicotinoylhydrazone) were synthesized. The spectroscopic and structural characterisation as well as their biological, properties are presented. 201606 2016 Institute of Chemistry of the Academy of Sciences of Moldova Ciloci, A.; Bivol, C.; Stratan, M.; Reva, V., Clapco, S.; Tiurin, J.; Rija, A.; Coropceanu, E. The effect of [Co(DH)2(An)2]2[TiF6]·3H2O coordination compound on polypeptide spectrum of amylolytic preparation from Aspergillus niger 33-19 CNMN FD 02a strain. The Annals of Oradea University, Biology Fascicle, 2012, 19(2), pp. 128-132 Clapco, S.; Bivol, C.; Ciloci, A.; Stratan, M.; Coropceanu, E.; Tiurin, J.; Rija, A.; Labliuc, S.; Bulhac, I. The effect of some metal complexes of oxime ligands on proteolytic activity of Fusarium gibbosum CNMN FD 12 strain. The Annals of Oradea University, Biology Fascicle, 2013, 20(1), pp. 53-58 Deseatnic-Ciloci, A.; Tiurina, J.; Ciapurina, L.; Turta, C.; Bivol, C.; Clapco, S.; Dvornina, E.; Labliuc, S. Coordination compounds of copper with aminoacids as potential stimulators of micromycetes extracellular hydrolases biosynthesis. Priorities of Chemistry for a Sustainable Development, PRIOCHEM, Bucharest, Romania, 2013, pp. 119-121 10.1134/S107032841311002X 10.19261/cjm.2008.03(2).15 10.1016/j.poly.2012.10.040 Bivol, C.; Lazarescu, A.; Turta, C.; Rudic, V. Action of some coordinative compounds of Fe(III) with α-aminoacids on photosynthetical pigments content in microalgae Dunaliella salina CVNMN-AV-01. Journal of Academy of Sciences of Moldova. Life sciences, 2012, 3(317), pp. 149-154. (in Romanian) Rudic, V.; Cepoi, L.; Rudi, L.; Miscu, V.; Chiriac, T.; Cojocari, A.; Lozan, V.; Coropceanu, E.; Bologa, O. Influence of coordinative compounds of cobalt with dioximates on biosynthetical processes in red alga Porphiridium cruentum. Journal of Academy of Sciences of Moldova. Life sciences, 2012, 1(316). pp. 144-151. (in Romanian) Rudi, L.; Cepoi, L.; Miscu, V.; Chiriac, T.; Valuta A.; Codreanu, S.; Sadovnic, D.; Rudic, V. Biomass and carotenoid production by green alga Haematococcus pluvialis during the life cycle under the infl uence of Co(II) Schiff base complexes. Journal of Academy of Sciences of Moldova. Life sciences, 2014, 2(323), pp. 163-171. (in Romanian) Valuta, A.; Cepoi, L.; Rudi, L.; Bulhac, I.; Bourosh, P.; Bologa, O. Phycobiliprotein accumulation in cyanobacterium Nostoc linckia and modification of antioxidant activity. The Annals of Oradea University, Biology Fascicle, 2015, 22(1), pp. 13-19 10.19261/cjm.2013.08(1).09 Usatii, A.; Topala, L.; Chirita, E. Calcatiniuc, A., Borisova, T. Productivity, lipidogenesis and carotinogensis of yeast Rhodotorula gracilis CNM-YS-III/20 at the cultivation in presence of coordinative compounds of Mo(IY), Cr(III), Co(III), V(V). Journal of Academy of Sciences of Moldova. Life sciences, 2003, 1, pp. 99-103. (in Romanian) 10.19261/cjm.2013.08(2).09 Ciloci, A.; Tiurina, J.; Bologa, O.; Clapco, S.; Labliuc, S.; Pasha, L.; Coropceanu, E.; Rija, A. Coordinative compounds of Mo and V as possible stimulators of biosynthesis of exocellular cellulases of micromycete Penicillium expansum CNMN FD 05 C. Journal of Academy of Sciences of Moldova. Life sciences, 2012, 3(318), pp. 158-165. (in Russian) Lemenovschi, D.A. Metalic composition in nature. Soros Educational Journal, 1997, 9, pp. 48-54. (in Russian) Ershov, Iu.A.; Pletneova, T.V. The chemistry of biogenic elements. Vysshaja shkola: Moscow, 1993, 560 p. (in Russian) Verejan, A.V. Coordination compounds of transition metals with semicarbazide diacetic acid and its derivatives. Ph.D. Thesis, A.V. Bogatskii Physico-Chemical Institute, Ukrainian Academy of Sciences, Odessa, Ukraine, 1991. (in Russian) Gerbeleu, N.V.; Verejan, A.V.; Byrca, M.C.; Turta, C.I.; Lozan, V.I.; Bologa, O.A. Mössbauer spectra of coordination compounds of iron(III) with semicarbazide diacetic acid and its dihydrazide. Proceedings of the VIth Conference on Spectroscopy of Coordination Compounds, Krasnodar, Russia, 1990, p. 170. (in Russian) 10.1107/S0108767307043930 Сiloci, A.; Tiurina, J.; Clapco, S.; Labliuc, S.; Stratan, M.; Grumeza, M. Fungal strain Aspergillus niger – producer of cellulozolytic and xylanolytic enzymes. MD Patent, 2010, No. 4072. (in Romanian) Haritonov, Iu.Y.; Machoshvili, R.I.; Gogorishvili, P.V.; Shamilishvili, O.H. Investigation of metal coordinative complexes with oxalyl dihydrazide by IR spectroscopy. Russian Journal of Inorganic Chemistry, 1972, 17(11), pp. 2992-2995. (in Russian) Haritonov, Iu.Y.; Machoshvili, R.I.; Goeva, L.V.; Scelokov, R.N. Metal coordinative compounds with diformyl hydrazine. Russian Journal of Coordinative Chemistry, 1975, 1(3), pp. 333-341. (in Russian) Nakamoto, K. IR spectra and Raman spectra of inorganic and organic coordinative compounds. Mir: Moscow, 1991, 536 p. (in Russian) Nakanisi, K. Infrared spectra and structure of organic compounds. Mir: Moscow, 1965, 216 p. (in Russian) Bellami, L. Infrared spectra of complex molecules. IL: Moscow, 1963, 590 p. (in Russian) Tarasevici, B.N. Infrared spectra of basic class of organic compounds. Reference materials. Moscow, 2012, 54 p. (in Russian) 10.1080/0095897021000058600 10.1021/ic50162a016 10.1107/S0108768102003890 10.1021/ic50182a014 10.1039/DT9900002771 10.1021/ic7012039 10.1039/C4CC10182K