ibn-ResPubl-45623 2016-06-22 11 1 39 1857-1727 https://ibn.idsi.md/ro/vizualizare_articol/45623 Structure and some biological properties of Fe(III) complexes with nitrogen-containing ligands iron complexes; nitrogen-containing ligands; structure; biological properties Four coordination compounds of iron(III) with ligands based on hydrazine and sulfadiazine: [Fe(dig)]Cl3·2H2O (I) (dig-semicarbazide diacetic acid dihydrazide), [Fe(HL)SO4] (II) (НL - sulfadiazine), [Fe(H2L1)(H2O)2](NO3)3·5H2O (III) (H2L1-2,6-diacetylpyridine bis(nicotinoylhydrazone) and [Fe(H2L2)(H2O)2](NO3)3·1.5H2O (IV) (H2L2 - 2,6-diacetylpyridine bis(isonicotinoylhydrazone) were synthesized. The spectroscopic and structure characterisation, as well as their biological properties, are presented. All tested coordination compounds, caused an inhibitory effect on the biosynthesis of hydrolases of the producer Aspergillus niger CNMN FD-10. The effect increased with the raise of the concentration from 5 mg/L to 15 mg/L. The complexes largely inhibited cellobiohydrolase and less- β-glucosidase. The inhibitory effect of the coordination compounds was quite similar in the case of endoglucanase and xylanase. Compound I, containing both chloride ions and dig, demonstrated a stronger inhibitory effect, while compound III, containing NO3 - ions, showed the weakest inhibitory action. eda2d9e9-34c5-11e1-b86c-0800200c9a66 759af938-34ae-11e1-b86c-0800200c9a66 2016-06-22T24:00:00 e601872f-4b7e-4d88-929f-7df027b226c9 40e90e2f-446d-460a-98e5-5dce57550c48 2016-06-22T24:00:00 ibn-person-10499 49815870-1cfe-11e1-8bc2-0800200c9a66 b7135ad0-1d00-11e1-8bc2-0800200c9a66 2016-06-22T24:00:00 ibn-person-20572 49815870-1cfe-11e1-8bc2-0800200c9a66 b7135ad0-1d00-11e1-8bc2-0800200c9a66 2016-06-22T24:00:00 ibn-person-197 49815870-1cfe-11e1-8bc2-0800200c9a66 b7135ad0-1d00-11e1-8bc2-0800200c9a66 2016-06-22T24:00:00 ibn-person-1357 49815870-1cfe-11e1-8bc2-0800200c9a66 b7135ad0-1d00-11e1-8bc2-0800200c9a66 2016-06-22T24:00:00 ibn-person-11139 49815870-1cfe-11e1-8bc2-0800200c9a66 b7135ad0-1d00-11e1-8bc2-0800200c9a66 2016-06-22T24:00:00 ibn-person-12574 49815870-1cfe-11e1-8bc2-0800200c9a66 b7135ad0-1d00-11e1-8bc2-0800200c9a66 2016-06-22T24:00:00 ibn-person-1210 49815870-1cfe-11e1-8bc2-0800200c9a66 b7135ad0-1d00-11e1-8bc2-0800200c9a66 2016-06-22T24:00:00 ibn-person-12192 49815870-1cfe-11e1-8bc2-0800200c9a66 b7135ad0-1d00-11e1-8bc2-0800200c9a66 2016-06-22T24:00:00 ibn-person-12514 49815870-1cfe-11e1-8bc2-0800200c9a66 b7135ad0-1d00-11e1-8bc2-0800200c9a66 2016-06-22T24:00:00 ibn-person-23814 49815870-1cfe-11e1-8bc2-0800200c9a66 b7135ad0-1d00-11e1-8bc2-0800200c9a66 2016-06-22T24:00:00 ibn-doi-45623 10.19261/cjm.2016.11(1).05 2016-06-22T24:00:00 31d222b4-11e0-434b-b5ae-088119c51189 bccb3266-689d-4740-a039-c96594b4d916 5123451 eda2b2e2-34c5-11e1-b86c-0800200c9a66 5a270628-f593-4ff4-a44a-95660c76e182 ibn-Pers-10499 ibn-PersName-10499-3 55f90543-d631-42eb-8d47-d8d9266cbb26 7375609d-cfa6-45ce-a803-75de69abe21f 2016-06-22T24:00:00 Bulhak Ion Булхак И.И. ibn-Pers-20572 ibn-PersName-20572-3 55f90543-d631-42eb-8d47-d8d9266cbb26 7375609d-cfa6-45ce-a803-75de69abe21f 2016-06-22T24:00:00 Десятник А ibn-Pers-197 ibn-PersName-197-3 55f90543-d631-42eb-8d47-d8d9266cbb26 7375609d-cfa6-45ce-a803-75de69abe21f 2016-06-22T24:00:00 Bourosh Paulina ibn-Pers-1357 ibn-PersName-1357-3 55f90543-d631-42eb-8d47-d8d9266cbb26 7375609d-cfa6-45ce-a803-75de69abe21f 2016-06-22T24:00:00 Тюрина Жанета ibn-Pers-11139 ibn-PersName-11139-3 55f90543-d631-42eb-8d47-d8d9266cbb26 7375609d-cfa6-45ce-a803-75de69abe21f 2016-06-22T24:00:00 Болога О. А. ibn-Pers-12574 ibn-PersName-12574-3 55f90543-d631-42eb-8d47-d8d9266cbb26 7375609d-cfa6-45ce-a803-75de69abe21f 2016-06-22T24:00:00 Бивол Чезара ibn-Pers-1210 ibn-PersName-1210-3 55f90543-d631-42eb-8d47-d8d9266cbb26 7375609d-cfa6-45ce-a803-75de69abe21f 2016-06-22T24:00:00 Клапко Светлана ibn-Pers-12192 ibn-PersName-12192-3 55f90543-d631-42eb-8d47-d8d9266cbb26 7375609d-cfa6-45ce-a803-75de69abe21f 2016-06-22T24:00:00 Вережан А.В. ibn-Pers-12514 ibn-PersName-12514-3 55f90543-d631-42eb-8d47-d8d9266cbb26 7375609d-cfa6-45ce-a803-75de69abe21f 2016-06-22T24:00:00 Лаблюк Светлана ibn-Pers-23814 ibn-PersName-23814-3 55f90543-d631-42eb-8d47-d8d9266cbb26 7375609d-cfa6-45ce-a803-75de69abe21f 2016-06-22T24:00:00 Danilescu Olga 5123451 CrossRef DOI prefix service The service of issuing DOI prefixes to publishers persistent identifier; Digital Object Identifier