A NEW 2D COORDINATION POLYMER BASED ON ZINC(II), 1,2,3-BENZENETRICARBOXYLIC ACID AND 4,4ʹ-BIS(IMIDAZOL-1-YLMETHYL)BIPHENYL: SYNTHESIS AND CRYSTAL STRUCTURE
Author(s):
Irina Voda
Field: Inorganic and coordination chemistry Type: Research paper Issue: 2023 Volume 18, no.1 Pages: 70-76
Abstract (PDF)
Graphical Abstract: The use of a pillar bridging ligand coordinating through two imidazole rings and multidentate carboxylate ligand with zinc(II) generates a bidimentional coordination polymer {[Zn3(BIBPh)3(BTC)2]∙H2O}n. It has been structurally characterised and investigated by IR and thermogravimetric methods. Each metal ion is four coordinated exhibiting a slightly distorted tetrahedral coordination.