Chemistry Journal of Moldova

A NEW 2D COORDINATION POLYMER BASED ON ZINC(II), 1,2,3-BENZENETRICARBOXYLIC ACID AND 4,4ʹ-BIS(IMIDAZOL-1-YLMETHYL)BIPHENYL: SYNTHESIS AND CRYSTAL STRUCTURE

Author(s):

Irina Voda


Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2023 Volume 18, no.1
Pages: 70-76
Keywords:

coordination polymer, X-ray diffraction, zinc, 1,2,3-benzenetricarboxylic acid, 4,4ʹ-bis(imidazol-1-ylmethyl)biphenyl.


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Abstract (PDF)
Graphical Abstract:
The use of a pillar bridging ligand coordinating through two imidazole rings and multidentate carboxylate ligand with zinc(II) generates a bidimentional coordination polymer {[Zn3(BIBPh)3(BTC)2]∙H2O}n. It has been structurally characterised and investigated by IR and thermogravimetric methods. Each metal ion is four coordinated exhibiting a slightly distorted tetrahedral coordination. 


 


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