Graphycal Abstract: The current study aims to maximize the recovery of antioxidant phenolics from Algerian Trifolium tomentosum L. using an innovative green process: ultrasonic assisted extraction (UAE). Using response surface methodology (RSM), the optimal UAE parameters for maximum responses (total phenolic content, total flavonoid content, and total antioxidant capacity) were 70% ethanol concentration, 30.4545 minutes of extraction time, and 75°C extraction temperature.
Nurfitrah Amran, Siti NurSyazwani Maadon, Yamin Yasin, Nik Rozlin Nik Masdek, Mohd Rafii Yusop, Nor Hazlina Mat Sa’at, Nor Monica Ahmad, Nor’Aishah Hasan
Graphycal Abstract: The present work explored the synthesis of ZnO nanoparticles using rice husk waste. The characterisation by UV-Vis spectroscopy suggested the formation of ZnO.
Analysis of X-Ray diffraction analysis (XRD) confirms the purity of the NPs with a crystallite size of less than 21 nm.Fourier transform infrared spectroscopy reveals the significance functional group at 487 cm-1.
Graphycal Abstract: The present study describes synthesis, research and definition of the structure of five new coordination compounds of Germanium(IV) and 3d-metals with 1-hydroxyethane-1,1-diphosphonic acid and 1,10-phenanthroline, which in crystals are organic-inorganic hybrid ensembles with three-dimensional networks formed by numerous intermolecular hydrogen bonds between complex cations, anions, and crystalline water molecules.
Graphycal Abstract: With ZnAl2O4@ZnO as a catalyst, an environmentally eco-friendly and highly effective method was developed for regio-and chemo-selective bis enamination of 1,3-dicarbonyl compounds and aromatic, aliphatic primary amines. A wide variety of bis-(β-enaminones) and bis-(β-enaminoesters) can be synthesized using this highly versatile method which offers good yields.
Graphycal Abstract: The essential oil of Marrubium deserti from Bechar (Algeria) was investigated to determine its chemical composition, physico-chemical characteristics,the antibacterial and antifungal activities. The findings showed that α-phellandrene (25.05%), β-pinene (14.05%), and α-pinene (12.83%) were the major compounds of this oil. Moreover, it was displayed that the studied essential oil has good antibacterial power as well as a strong inhibitory effect on spore sporulation, germination, and pathogen fungus development.
https://doi.org/10.19261/cjm.2024.1212
Graphycal Abstract: Two new compounds – a mononuclear nickel(II) compound with di-paratolylglyoxime (DpatH2) - [Ni(DpatH2)3]SO4∙1,4-H2bdc∙2.5DMF∙H2O (1) and a binuclear manganese(II) compound with dianilineglyoxime (DAnH2) - [Mn2(DAnH2)2(1,3-bdc)2(DMSO)4] (2) (1,4- and 1,3-bdc are 1,4- and 1,3-benzenedicarboxylic acids, respectively) have been obtained. The IR spectra of the complexes were studied and molecular and crystal structures of the compounds were determined by single crystal X-ray diffraction method. Compound 1 is ionic and contains a complex cation in which three neutral DpatH2 ligands are coordinated to the nickel atom. Complex 2 is a molecular binuclear complex in which, in addition to the two neutral ligands DAnH2 and four DMSO, two 1,3-benzenedicarboxylic anions are coordinated to the metal atoms in a bridging manner.