Chemistry Journal of Moldova

Accepted papers

Kyrylo Tsymbaliuk, Оlena Martsynko, Viktoriya Dyakonenko, Оlena Finik, Inna Seifullina, Svitlana Shishkina

Field: Inorganic and coordination chemistry
Type: Research paper
1-hydroxyethane-1,1-diphosphonic acid, nitrogen heterocycle, germanium, 3d-metal, crystal structure.
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https://doi.org/10.19261/cjm.2024.1247

Graphycal Abstract: The present study describes synthesis, research and definition of the structure of five new coordination compounds of Germanium(IV) and 3d-metals with 1-hydroxyethane-1,1-diphosphonic acid and 1,10-phenanthroline, which in crystals are organic-inorganic hybrid ensembles with three-dimensional networks formed by numerous intermolecular hydrogen bonds between complex cations, anions, and crystalline water molecules.



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Mohamed Loughzail, Koffi Senam Etsè, Zaragoza Verez Guillermo, Rachid Touzani, Anna Moliterni, Mohamed Anouar Harrad, Abdessamad Tounsi

Field: Organic chemistry
Type: Research paper
β-enaminoester; X-ray diffraction, monoclinic space, Hirshfeld surface, ADMET-Tox.
 
https://doi.org/10.19261/cjm.2024.1220

Graphycal Abstract: The compound 3-(2,4,6-timethyl-phenylamino)-but-2-enoate was obtained by the condensation reaction of ethyl acetoacetate and 2,4,6-trimethyl-phenylamine. X-ray structural analysis identified the structure of the synthesized β-enaminoester, NMR spectroscopy complemented it, and the structure stabilised by intramolecular interactions. The intermolecular contacts were further analysed by the mapping of contacts descriptors dnorm, de, di, the shape-by-shape index and surface property by electrostatic potential mapped on the Hirshfeld surface (HS). Data from density functional theory (DFT) was compared to experimental results for this process. Global reactivity factors such as electronegativity, chemical hardness, potential, and softness were calculated using DFT. The effects of the molecular environment were accessed by analysing the electrostatic potentials surface mapped over the HS and the 3D-topology of energy frameworks. As a potential bioactive molecule, the physicochemical and ADME-Tox predictions were performed suggesting that compound 3 could be considered a promising drug candidate. 


Lyubov Patrylak, Serhiy Konovalov, Stepan Zubenko, Angela Yakovenko, David Davitadze, Olexandra Pertko

Field: Natural product chemistry and synthesis
Type: Research paper
fatty acid ethyl esters, purification, sorbents, distillation and ion exchange resins.
 
https://doi.org/10.19261/cjm.2024.1236

Graphycal Abstract: The efficiency of removing glycerol, soaps, and unconverted acylglycerols from crude fatty acid ethyl esters by different techniques was evaluated. The proposed purification scheme allows for obtaining a product that meets the quality indicators of EN 14214 and can be used as a biodiesel fuel component.


Radia Hannache, Radia Ayad, Nassima Boutaoui, Hayat Bourekoua, Mostefa Lefahal, El Hani Makhloufi, Nabila Souilah, Salah Akkal, Kamel Medjroubi

Field: Natural product chemistry and synthesis
Type: Research paper
Trifolium tomentosum, green process, ultrasonic, response surface methodology, antioxidant phenolics.
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https://doi.org/10.19261/cjm.2024.1221

Graphycal Abstract: The current study aims to maximize the recovery of antioxidant phenolics from Algerian Trifolium tomentosum L. using an innovative green process: ultrasonic assisted extraction (UAE). Using response surface methodology (RSM), the optimal UAE parameters for maximum responses (total phenolic content, total flavonoid content, and total antioxidant capacity) were 70% ethanol concentration, 30.4545 minutes of extraction time, and 75°C extraction temperature.



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Nurfitrah Amran, Siti NurSyazwani Maadon, Yamin Yasin, Nik Rozlin Nik Masdek, Mohd Rafii Yusop, Nor Hazlina Mat Sa’at, Nor Monica Ahmad, Nor’Aishah Hasan

Field: Ecological chemistry
Type: Research paper
rice husk waste, Oryza sativa, zinc oxide, nanoparticles, antibacterial activity.
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https://doi.org/10.19261/cjm.2024.1196

Graphycal Abstract:
 The present work explored the synthesis of ZnO nanoparticles using rice husk waste. The characterisation by UV-Vis spectroscopy suggested the formation of ZnO.
Analysis of X-Ray diffraction analysis (XRD) confirms the purity of the NPs with a crystallite size of less than 21 nm.Fourier transform infrared spectroscopy reveals the significance functional group at 487 cm-1.
 




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Mohamed Anouar Harrad, Adnan Semane, Mohammed Badereddine, Abdessamad Tounsi

Field: Organic chemistry
Type: Research paper
bis-(β-enaminoester), bis-(β-enaminone), free solvent condition, condensation, catalyst heterogeneous.
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https://doi.org/10.19261/cjm.2024.1199

Graphycal Abstract: With ZnAl2O4@ZnO as a catalyst, an environmentally eco-friendly and highly effective method was developed for regio-and chemo-selective bis enamination of 1,3-dicarbonyl compounds and aromatic, aliphatic primary amines. A wide variety of bis-(β-enaminones) and bis-(β-enaminoesters) can be synthesized using this highly versatile method which offers good yields.






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Amina Mazeri, Achraf Khaldi, Mehdi Kheira, Adel Benarfa, Hadjer Saber

Field: Natural product chemistry and synthesis
Type: Research paper
chemical composition, essential oil, Marrubium deserti de Noé, antibacterial, antifungal.
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https://doi.org/10.19261/cjm.2024.1219

Graphycal Abstract: The essential oil of Marrubium deserti from Bechar (Algeria) was investigated to determine its chemical composition, physico-chemical characteristics,the antibacterial and antifungal activities. The findings showed that α-phellandrene (25.05%), β-pinene (14.05%), and α-pinene (12.83%) were the major compounds of this oil. Moreover, it was displayed that the studied essential oil has good antibacterial power as well as a strong inhibitory effect on spore sporulation, germination, and pathogen fungus development.




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Dumitru Ureche, Ion Bulhac, Pavlina Bourosh

Field: Inorganic and coordination chemistry
Type: Research paper
coordination compound, Ni(II), Mn(II), dioxime, X-ray study, hydrogen bond.
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https://doi.org/10.19261/cjm.2024.1212

Graphycal Abstract:
Two new compounds – a mononuclear nickel(II) compound with di-paratolylglyoxime (DpatH2) - [Ni(DpatH2)3]SO4∙1,4-H2bdc∙2.5DMF∙H2O (1) and a binuclear manganese(II) compound with dianilineglyoxime (DAnH2) - [Mn2(DAnH2)2(1,3-bdc)2(DMSO)4] (2) (1,4- and 1,3-bdc are 1,4- and 1,3-benzenedicarboxylic acids, respectively) have been obtained. The IR spectra of the complexes were studied and molecular and crystal structures of the compounds were determined by single crystal X-ray diffraction method. Compound 1 is ionic and contains a complex cation in which three neutral DpatH2 ligands are coordinated to the nickel atom. Complex 2 is a molecular binuclear complex in which, in addition to the two neutral ligands DAnH2 and four DMSO, two 1,3-benzenedicarboxylic anions are coordinated to the metal atoms in a bridging manner.




Downloads: 4