Graphical Abstract: In the context of studies conducted in the laboratory of National Center for Quality Testing of the Alcoholic Beverages (Republic of Moldova) were included more than 1300 samples of the bottled wine and base-wine for the presence of most widespread and toxic phthalate – dibutylphthalate using modern method of analysis like GC-MS. Results display presences DBP in 85 % of studied samples of wines, i.e. a content of DBP more than LOQ (0.01mg/dm3). Has been determined that contamination of phthalates has a technogenic character, and it is the result of contact with polymeric materials. Optimum conditions of extraction DBP from liquid samples were obtained.