Chemistry Journal of Moldova

SYNTHESIS, CRYSTAL STRUCTURE AND MAGNETIC BEHAVIOUR OF NOVEL 4f-2s HETEROMETALIC ONE-DIMENSIONAL COORDINATION POLYMERS ON THE BASE OF 2-FURAN-CARBOXYLIC ACID

Author(s):

Silvia Melnic, Denis Prodius, Sergiu Shova, Helen Stoeckli-Evans, Yurii Simonov, Alexandr Feher, Maria Gdaniec, Constantin Turta


Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2009 Volume 4, no.2
Pages: 60-67
Keywords:

heteronuclear lanthanide (III) complexes, furancarboxylates ligand, crystal structure, magnetic properties.


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DOI:
dx.doi.org/10.19261/cjm.2009.04(2).10

Graphical Abstract:
 Nine new complexes with the general formula {[Ln2Ba(α-Fur)8(H2O)4]}n, where Ln = Nd3+, Sm3+Eu3+, Pr3+, Gd3+, Tb3+, Ho3+, Er3+ and La3+; α-Fur ≡ C4H3OCOO, were synthesized and characterized by IR spectra, magnetism, X-ray single crystal and powder diffractions.


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