SYNTHESIS, CRYSTAL STRUCTURE AND MAGNETIC BEHAVIOUR OF NOVEL 4f-2s HETEROMETALIC ONE-DIMENSIONAL COORDINATION POLYMERS ON THE BASE OF 2-FURAN-CARBOXYLIC ACID
Author(s):
Silvia Melnic, Denis Prodius, Sergiu Shova, Helen Stoeckli-Evans, Yurii Simonov, Alexandr Feher, Maria Gdaniec, Constantin Turta
Field: Inorganic and coordination chemistry Type: Research paper Issue: 2009 Volume 4, no.2 Pages: 60-67
Keywords:
heteronuclear lanthanide (III) complexes, furancarboxylates ligand, crystal structure, magnetic properties.
Graphical Abstract:Nine new complexes with the general formula {[Ln2Ba(α-Fur)8(H2O)4]}n,where Ln = Nd3+, Sm3+, Eu3+, Pr3+, Gd3+, Tb3+, Ho3+, Er3+ and La3+; α-Fur ≡ C4H3OCOO, were synthesized and characterized by IR spectra, magnetism, X-ray single crystal and powder diffractions.