Chemistry Journal of Moldova

THE ROLE OF HALOGEN BONDING IN THE SYNTHESIS AND DESIGN OF TAP COMPLEXES

Author(s):

Namiq Shikhaliyev, Ayten Niyazova, Abel Maharramov, Agaisa Askerov, Nazrin Zeynalli, Viktor Krustalev, Peri Huseynova


Field: Inorganic and coordination chemistry
Type: Review
Pages:
Keywords:

halogen bonding; TAP complex; 1,3,5-triazapentadiene; noncovalent interaction; σ-hole.


  
https://doi.org/10.19261/cjm.2026.1499
 
Abstract (PDF)
Graphycal Abstract: This review highlights the crucial role of halogen bonding in governing the synthesis, crystal engineering, and supramolecular self-assembly of 1,3,5-triazapentadiene (TAP) metal complexes. It covers synthetic strategies, the σ-hole model, cooperative non-covalent interactions, and diverse functional applications including catalysis and material design.