Chemistry Journal of Moldova
- SCOPUS Journal Metrics for year 2023:
- CiteScore 0.9;
- Source Normalized Impact per Paper (SNIP) 0.094;
- SCImago Journal Rank (SJR) 0.133.
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NANOPARTICLES
Mihail Iacob
(downloads: 1156)
2. SYNTHESIS OF DIFFERENT STRUCTURAL TYPES
OF ZEOLITES IN THE
HALLOYSITE-DOLOMITE-OBSIDIAN SYSTEM
Gunel Mamedova
(downloads: 782)
3. A NOVEL GREEN SYNTHESIS OF NICKEL OXIDE
NANOPARTICLES USING ARABIC GUM
Saeid Taghavi Fardood, Ali Ramazani, Sajjad Moradi
(downloads: 662)
4. SYNTHESIS, CHARACTERIZATION AND
MOLECULAR DOCKING OF CHLORO-SUBSTITUTED
HYDROXYXANTHONE DERIVATIVES
Emmy Yuanita, Harno Dwi Pranowo, Mustofa Mustofa, Respati Tri Swasono, Jufrizal Syahri, Jumina Jumina
(downloads: 517)
5. ROLE OF CYCLODEXTRINS IN NEW
ANTIMYCOBACTERIAL FORMULATIONS
Veaceslav Boldescu, Fliur Macaev, Gheorghe Duca
(downloads: 470)
6. SILVER AND ZINC NANOPARTICLES
BIOSYNTHESIS USING LAUREL EXTRACT AND
INVESTIGATION OF THE PHOTOCATALYTIC
PROPERTIES
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ENT-KAURENOIC ACID
Olga Morarescu
(downloads: 427)
8. INVESTIGATION OF VARIOUS INFLUENCING
FACTORS OF HYDROTHERMAL SYNTHESIS OF
ANALCIME ZEOLITE
Gunel Mamedova, Gunel Nasirli
(downloads: 425)
9. STUDIES ON THE WATER SOLUBILIZATION
PROCESSES OF OENOTANNINS AND THEIR
PHYSICO-CHEMICAL PROPERTIES
Gh. Duca, T. Lupaşcu, P. Vlad, V. Kulciţki, R. Nastas
(downloads: 413)
10. ORGANOCHLORINE PESTICIDES RESIDUES IN
SOIL OF SOROCA DISTRICT, REPUBLIC OF
MOLDOVA
Elena Culighin
(downloads: 384)
ACTIVATION OF ACETYLENE BY COORDINATION TO BIS-TRIPHENYLPHOSPHINE COMPLEX OF Pt(0): DFT STUDY
Author(s):
Field: Physical chemistry and chemical physics
Type: Research paper
Issue: 2009 Volume 4, no.1
Pages: 123-128
N. N. Gorinchoy, B. Dobrova, M. Yu. Gorbachev, G. Munteanu, and I. Ya. Ogurtsov
Field: Physical chemistry and chemical physics
Type: Research paper
Issue: 2009 Volume 4, no.1
Pages: 123-128
chemical activation, quantum-chemical calculations, DFT method.
Full Text (PDF): Download
DOI: dx.doi.org/10.19261/cjm.2009.04(1).01
Graphical Abstract: The present work is devoted to the theoretical study of the activation of the acetylene molecule coordinated in the [Pt(PPh3)2C2H2] complex. By means of DFT calculations it is shown that the geometrical and electronic characteristics of the C2H2 are essentially changed due to its coordination. The subsequent detailed analysis of the molecular orbitals (MO) of the active valence zone of this complex allows one to make important conclusion that this activation is being realized mainly due to the orbital back donation of 5d-electronic density from one of the occupied MOs of the complex [Pt(PPh3)2] to the unoccupied antibonding π*-MO of C2H2.
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