Chemistry Journal of Moldova
- SCOPUS Journal Metrics for year 2023:
- CiteScore 0.9;
- Source Normalized Impact per Paper (SNIP) 0.094;
- SCImago Journal Rank (SJR) 0.133.
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NANOPARTICLES
Mihail Iacob
(downloads: 1156)
2. SYNTHESIS OF DIFFERENT STRUCTURAL TYPES
OF ZEOLITES IN THE
HALLOYSITE-DOLOMITE-OBSIDIAN SYSTEM
Gunel Mamedova
(downloads: 782)
3. A NOVEL GREEN SYNTHESIS OF NICKEL OXIDE
NANOPARTICLES USING ARABIC GUM
Saeid Taghavi Fardood, Ali Ramazani, Sajjad Moradi
(downloads: 662)
4. SYNTHESIS, CHARACTERIZATION AND
MOLECULAR DOCKING OF CHLORO-SUBSTITUTED
HYDROXYXANTHONE DERIVATIVES
Emmy Yuanita, Harno Dwi Pranowo, Mustofa Mustofa, Respati Tri Swasono, Jufrizal Syahri, Jumina Jumina
(downloads: 517)
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ANTIMYCOBACTERIAL FORMULATIONS
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(downloads: 425)
9. STUDIES ON THE WATER SOLUBILIZATION
PROCESSES OF OENOTANNINS AND THEIR
PHYSICO-CHEMICAL PROPERTIES
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(downloads: 413)
10. ORGANOCHLORINE PESTICIDES RESIDUES IN
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COMPUTATIONAL INSIGHTS INTO THE SPONTANEITY OF EPOXIDE FORMATION FROM HALOHYDRINS AND OTHER MECHANISTIC DETAILS OF WILLIAMSON’S ETHER SYNTHESIS
Author(s):
Field: Physical chemistry and chemical physics
Type: Research paper
Issue: 2023 Volume 18, no.2
Pages: 87-95
Pedro Silva
Field: Physical chemistry and chemical physics
Type: Research paper
Issue: 2023 Volume 18, no.2
Pages: 87-95
density-functional theory, reaction mechanisms, intra-molecular Williamson’s ether synthesis, epoxide, halohydrin.
Full Text (PDF): Download
Abstract (PDF)
Graphical Abstract: DFT computations identify the effects that enable the synthesis of geometrically-strained epoxide from deprotonated halohydrins. These computations also explain the preference for the formation of larger cyclic ethers with five-atom rings over six-atom-rings. Increased temperature favors elimination over SN2 only when the reacting moieties are part of separate molecules.
Graphical Abstract: DFT computations identify the effects that enable the synthesis of geometrically-strained epoxide from deprotonated halohydrins. These computations also explain the preference for the formation of larger cyclic ethers with five-atom rings over six-atom-rings. Increased temperature favors elimination over SN2 only when the reacting moieties are part of separate molecules.
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