Chemistry Journal of Moldova

GEOMETRICAL ISOMERISM IN Ru2Au HETEROMETAL ASSEMBLY: CIS-LINKING OF TETRACYANIDOAURATE TO TETRAKIS(µ-BUTANOATO)DIRUTHENIUM

Author(s):

Masahiro Mikuriya, Shun Kawauchi, Ryoji Mitsuhashi, Motohiro Tsuboi, Makoto Handa


Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2023 Volume 18, no.1
Pages: 77-85
Keywords:

dinuclear ruthenium carboxylate, tetracyanidoaurate, heterometal complex, X-ray crystallography, magnetic property.


Full Text (PDF): Download

https://doi.org/10.19261/cjm.2023.1059

Abstract (PDF)
Graphical Abstract:
A heterometal complex [RuIIRuIII(n-C3H7COO)4AuIII(CN)4]n was synthesized. The X-ray crystallography elucidated a chain molecule of alternating arrangement of Ru2(n-C3H7COO)4+ and Au(CN)4– units with cis-bridging mode. Magnetic susceptibility data showed that magnetic interaction between RuIIRuIII units (S= 3/2) is negligible small with a zero-field splitting parameter D of 60 cm–1







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