Graphical Abstract: Mineral waters of Russia, the CIS countries (Ukraine, Belarus, Moldova, Armenia, Azerbaijan, Georgia and Uzbekistan) and EU (Germany, France, Italy, Spain and some East European countries) carried to Chloride-Hydrocarbonate type have been investigated in this work. The analytical dependences connecting, entered by authors, characteristic parameters of structure of waters (В, Ф, R) with independent variables of ionic structure and concentration are resulted.