Graphical Abstract: Investigations found HCH and DDT residuals in bottom sediments from several reservoirs and lakes as well as the main rivers, Nistru and Prut (concentrations ranged between 0.2 and 15.8 ppb). The concentration of PCBs in the topsoil collected beneath the capacitors battery at the Vulcănesti substation reached a level of 7100 ppm which is exceeding the MAC by five orders of magnitude (!). With no exception, allowable concentrations of PCBs in soil were exceeded also on the territory of other investigated substations, with peaks registered at the Briceni substation (2545 ppm) and the Orhei substation (1959 ppm).