Chemistry Journal of Moldova
- SCOPUS Journal Metrics for year 2023:
- CiteScore 0.9;
- Source Normalized Impact per Paper (SNIP) 0.094;
- SCImago Journal Rank (SJR) 0.133.
TOP DOWNLOADED ARTICLES
1. SONOCHEMICAL SYNTHESIS OF HEMATITE
NANOPARTICLES
Mihail Iacob
(downloads: 1148)
2. SYNTHESIS OF DIFFERENT STRUCTURAL TYPES
OF ZEOLITES IN THE
HALLOYSITE-DOLOMITE-OBSIDIAN SYSTEM
Gunel Mamedova
(downloads: 782)
3. A NOVEL GREEN SYNTHESIS OF NICKEL OXIDE
NANOPARTICLES USING ARABIC GUM
Saeid Taghavi Fardood, Ali Ramazani, Sajjad Moradi
(downloads: 657)
4. SYNTHESIS, CHARACTERIZATION AND
MOLECULAR DOCKING OF CHLORO-SUBSTITUTED
HYDROXYXANTHONE DERIVATIVES
Emmy Yuanita, Harno Dwi Pranowo, Mustofa Mustofa, Respati Tri Swasono, Jufrizal Syahri, Jumina Jumina
(downloads: 513)
5. ROLE OF CYCLODEXTRINS IN NEW
ANTIMYCOBACTERIAL FORMULATIONS
Veaceslav Boldescu, Fliur Macaev, Gheorghe Duca
(downloads: 469)
6. SYNTHETIC TRANSFORMATIONS OF
ENT-KAURENOIC ACID
Olga Morarescu
(downloads: 426)
7. INVESTIGATION OF VARIOUS INFLUENCING
FACTORS OF HYDROTHERMAL SYNTHESIS OF
ANALCIME ZEOLITE
Gunel Mamedova, Gunel Nasirli
(downloads: 422)
8. STUDIES ON THE WATER SOLUBILIZATION
PROCESSES OF OENOTANNINS AND THEIR
PHYSICO-CHEMICAL PROPERTIES
Gh. Duca, T. Lupaşcu, P. Vlad, V. Kulciţki, R. Nastas
(downloads: 411)
9. ORGANOCHLORINE PESTICIDES RESIDUES IN
SOIL OF SOROCA DISTRICT, REPUBLIC OF
MOLDOVA
Elena Culighin
(downloads: 381)
10. DESIGN AND SYNTHESIS OF TWO
BICYCLO[3.3.1]NONANE-STEROID
DERIVATIVES
Lauro Figueroa, Alejandra Garcimarero, Rolando Garcia, Francisco Diaz, Marcela Rosas, Virginia Mateu, Maria Lopez, Lenin Hau, Tomas Lopez, Abelardo Camacho, Yaritza Borges
(downloads: 362)
NANOPARTICLES
Mihail Iacob
(downloads: 1148)
2. SYNTHESIS OF DIFFERENT STRUCTURAL TYPES
OF ZEOLITES IN THE
HALLOYSITE-DOLOMITE-OBSIDIAN SYSTEM
Gunel Mamedova
(downloads: 782)
3. A NOVEL GREEN SYNTHESIS OF NICKEL OXIDE
NANOPARTICLES USING ARABIC GUM
Saeid Taghavi Fardood, Ali Ramazani, Sajjad Moradi
(downloads: 657)
4. SYNTHESIS, CHARACTERIZATION AND
MOLECULAR DOCKING OF CHLORO-SUBSTITUTED
HYDROXYXANTHONE DERIVATIVES
Emmy Yuanita, Harno Dwi Pranowo, Mustofa Mustofa, Respati Tri Swasono, Jufrizal Syahri, Jumina Jumina
(downloads: 513)
5. ROLE OF CYCLODEXTRINS IN NEW
ANTIMYCOBACTERIAL FORMULATIONS
Veaceslav Boldescu, Fliur Macaev, Gheorghe Duca
(downloads: 469)
6. SYNTHETIC TRANSFORMATIONS OF
ENT-KAURENOIC ACID
Olga Morarescu
(downloads: 426)
7. INVESTIGATION OF VARIOUS INFLUENCING
FACTORS OF HYDROTHERMAL SYNTHESIS OF
ANALCIME ZEOLITE
Gunel Mamedova, Gunel Nasirli
(downloads: 422)
8. STUDIES ON THE WATER SOLUBILIZATION
PROCESSES OF OENOTANNINS AND THEIR
PHYSICO-CHEMICAL PROPERTIES
Gh. Duca, T. Lupaşcu, P. Vlad, V. Kulciţki, R. Nastas
(downloads: 411)
9. ORGANOCHLORINE PESTICIDES RESIDUES IN
SOIL OF SOROCA DISTRICT, REPUBLIC OF
MOLDOVA
Elena Culighin
(downloads: 381)
10. DESIGN AND SYNTHESIS OF TWO
BICYCLO[3.3.1]NONANE-STEROID
DERIVATIVES
Lauro Figueroa, Alejandra Garcimarero, Rolando Garcia, Francisco Diaz, Marcela Rosas, Virginia Mateu, Maria Lopez, Lenin Hau, Tomas Lopez, Abelardo Camacho, Yaritza Borges
(downloads: 362)
STRUCTURAL DISTORTIONS OF COORDINATED KETENE MOLECULE INDUCED BY THE PSEUDO JAHN-TELLER EFFECT
Author(s):
Field: Physical chemistry and chemical physics
Type: Research paper
Issue: 2016 Volume 11, no.2
Pages: 99-104
Natalia Gorinchoy
Field: Physical chemistry and chemical physics
Type: Research paper
Issue: 2016 Volume 11, no.2
Pages: 99-104
Pseudo Jahn-Teller effect, orbital charge transfers, ketene excited states, metal ketene complex.
Full Text (PDF): Download
Graphical Abstract: It is shown that the only reason of structural distortions of ketene molecule coordinated in the complexes VCp2-H2C2O (I) and Pt(PPh3)2-H2C2O (II) is the pseudo Jahn-Teller effect induced by the orbital charge transfers by coordination. The η2-(C-O) coordination and the in-plane distortion of ketene in the complex (I) is due to the PJTE induced by the back donation to its LUMO 3b2. The η2-(C-C) coordination mode, and the out-of-plane distortion of the molecule in the complex (II) is caused by two OSTs: from the HOMO 2b1 to the metal, and from the dxy-AO of Pt to the vacant 3b1 MO of ketene, thus being the result of the diorbital Pt-ketene interaction.
Downloads: 44