Chemistry Journal of Moldova

SYNTHESIS AND SPECTROSCOPIC STUDY OF SOME COORDINATIVE COMPOUNDS OF Co(III), Ni(II) AND Cu(II) WITH DIANILINE- AND DISULFANILAMIDEGLYOXIME

Author(s):

Andrei Rija, Ion Bulhac, Eduard Coropceanu, Elena Gorincioi, Elena Calmîc, Alic Barbă, Olga Bologa


Field: Organic chemistry
Type: Research paper
Issue: 2011 Volume 6, no.2
Pages: 73-78
Keywords:

α-dioximes, coordinative compounds, 3d metals, spectroscopy.


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DOI:
dx.doi.org/10.19261/cjm.2011.06(2).16

Graphical Abstract: 
Directed synthesis of dianiline- (DAnH2) and disulfanilamideglyoximes (DSamH2) has been accomplished by condensation of dichloroglyoxime with aniline or sulfanilamide in 1:2 molar ratio, as well as their corresponding Co(III), Ni(II) and Cu(II) coordinative compounds. Composition, structure and some properties of dioximes and complexes have been established by using elemental analysis, UV-Vis, IR and NMRspectroscopies. Dioxime coordination at the central atom and structure of complexes depends on pH of reaction medium: at pH=5-6 - bis-dioximates, whilst at pH=2 – tris-dioximines are obtained.


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