Chemistry Journal of Moldova

THE STUDY OF THE BIOLOGICAL ACTIVITY OF SOME COBALT(III) DIOXIMATES WITH FLUORINE CONTAINING ANIONS

Author(s):

Eduard Coropceanu, Alexandra Deseatnic, Maria Stratan, Andrei Rija, Olga Bologa, Janna Tiurin, Svetlana Labliuc, Steliana Clapco, Ion Bulhac


Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2008 Volume 3, no.2
Pages: 70-80
Keywords:

Co(III) dioximates, anions with fluorine, models of biological objects, biostimulating properties, fungi, enzymes.


Full Text (PDF): Download

DOI:
dx.doi.org/10.19261/cjm.2008.03(2).15

Graphical Abstract:
 It was elaborated the methodology of synthesizing a series of new dioximates of Co(III) with the general formula [Co(DioxH)2(L)2]X⋅nH2O, where DioxH – the dioxime anione: dimethylglyoxime (DH2), 1,2-cyclohexanedionedioxime (NioxH2); L - thiocarbamide (Thio), pyridine (Py), aniline (An), sulphanilamide (Sam);X - [BF4]-, [ZrF6]2-, [TiF6]2-, whose structures have been studied with the help of contemporary physical methods: spectroscopy IR, UV-Vis, RMN 1H, 19F, X-ray analysis. There were elaborated optimal conditions of using cobalt dioximates with fluorine in order to intensify the biosynthesis of amylases and lipases by Aspergillus and Rhizopus strains, respectively. The tested compounds increase the lipolytic activity of Rhizopus arrhisus micromycetes.


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