Chemistry Journal of Moldova
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Mihail Iacob
(downloads: 1148)
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OF ZEOLITES IN THE
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Gunel Mamedova
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THE NATURE OF THE Co-C BOND CLEAVAGE PROCESSES IN METHYLCOB(II)ALAMIN AND ADENOSYLCOB(III)ALAMIN
Author(s):
Field: Physical chemistry and chemical physics
Type: Review
Issue: 2016 Volume 11, no.1
Pages: 10-20
Tudor Spataru, Francisco Fernandez
Field: Physical chemistry and chemical physics
Type: Review
Issue: 2016 Volume 11, no.1
Pages: 10-20
vitamin B12, mechanism, bio-catalysis, Pseudo-Jahn-Teller effect, DFT, MCSCF.
Full Text (PDF): Download
DOI: dx.doi.org/10.19261/cjm.2016.11(1).01
Graphical Abstract: No grounded mechanisms for Co-C vitamin B12 coenzyme bond breaking process and subsequent reactions have been found up to now. The influence of the mixing orbitals e.g. Pseudo-Jahn-Teller and similar effects on the reactions paths of bond-cleavage mechanisms of vitamin B12 co-factors must be taken into account. Afterward, the updated mechanisms of vitamin B12 bio-processes can be determined.
The article is Open Access by CC-BY 4.0 License
Cite this article as: T. Spataru, F. Fernandez. The Nature of The Co-C Bond Cleavage Processes in Methylcob(II)Alamin and Adenosylcob(III)Alamin. Chemistry Journal of Moldova, 2016, 11(1), pp. 10-20. DOI: dx.doi.org/10.19261/cjm.2016.11(1).01
Article Source: The Nature of The Co-C Bond Cleavage Processes in Methylcob(II)Alamin and Adenosylcob(III)Alamin.
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