STRUCTURE AND SOME BIOLOGICAL PROPERTIES OF Fe(III) COMPLEXES WITH NITROGEN-CONTAINING LIGANDS
Author(s):
Ion Bulhac, Alexandra Deseatnic-Ciloci, Paulina Bourosh, Janetta Tiurina, Olga Bologa, Cezara Bivol, Steliana Clapco, Ana Verejan, Svetlana Labliuc, Olga Danilescu
Field: Inorganic and coordination chemistry Type: Research paper Issue: 2016 Volume 11, no.1 Pages: 39-49
Keywords:
iron complexes, nitrogen-containing ligands, structure, biological properties.
Graphical Abstract: Four coordination compounds of iron(III) with ligands based on hydrazine and sulfadiazine: FeCl3·digsemi·2H2O (I) (digsemi-semicarbazide diacetic acid dihydrazide, [Fe(HL)SO4] (II) (НL - sulfadiazine), [Fe(H2L1)(H2O)2](NO3)3·5H2O (III) (H2L1-2,6-diacetylpyridine bis(nicotinoylhydrazone) and [Fe(H2L2)(H2O)2](NO3)3•1.5H2O (IV) (H2L2 - 2,6-diacetylpyridine bis(isonicotinoylhydrazone) were synthesized. The spectroscopic and structural characterisation as well as their biological, properties are presented.