Chemistry Journal of Moldova
- SCOPUS Journal Metrics for year 2021:
- CiteScore 1.5;
- Source Normalized Impact per Paper (SNIP) 0.531;
- SCImago Journal Rank (SJR) 0.195.
TOP DOWNLOADED ARTICLES
1. SONOCHEMICAL SYNTHESIS OF HEMATITE
NANOPARTICLES
Mihail Iacob
(downloads: 1034)
2. SYNTHESIS OF DIFFERENT STRUCTURAL TYPES
OF ZEOLITES IN THE
HALLOYSITE-DOLOMITE-OBSIDIAN SYSTEM
Gunel Mamedova
(downloads: 725)
3. A NOVEL GREEN SYNTHESIS OF NICKEL OXIDE
NANOPARTICLES USING ARABIC GUM
Saeid Taghavi Fardood, Ali Ramazani, Sajjad Moradi
(downloads: 514)
4. ROLE OF CYCLODEXTRINS IN NEW
ANTIMYCOBACTERIAL FORMULATIONS
Veaceslav Boldescu, Fliur Macaev, Gheorghe Duca
(downloads: 445)
5. SYNTHESIS, CHARACTERIZATION AND
MOLECULAR DOCKING OF CHLORO-SUBSTITUTED
HYDROXYXANTHONE DERIVATIVES
Emmy Yuanita, Harno Dwi Pranowo, Mustofa Mustofa, Respati Tri Swasono, Jufrizal Syahri, Jumina Jumina
(downloads: 411)
6. SYNTHETIC TRANSFORMATIONS OF
ENT-KAURENOIC ACID
Olga Morarescu
(downloads: 400)
7. INVESTIGATION OF VARIOUS INFLUENCING
FACTORS OF HYDROTHERMAL SYNTHESIS OF
ANALCIME ZEOLITE
Gunel Mamedova, Gunel Nasirli
(downloads: 391)
8. STUDIES ON THE WATER SOLUBILIZATION
PROCESSES OF OENOTANNINS AND THEIR
PHYSICO-CHEMICAL PROPERTIES
Gh. Duca, T. Lupaşcu, P. Vlad, V. Kulciţki, R. Nastas
(downloads: 385)
9. ORGANOCHLORINE PESTICIDES RESIDUES IN
SOIL OF SOROCA DISTRICT, REPUBLIC OF
MOLDOVA
Elena Culighin
(downloads: 346)
10. THE NATURE OF THE Co-C BOND CLEAVAGE
PROCESSES IN METHYLCOB(II)ALAMIN AND
ADENOSYLCOB(III)ALAMIN
Tudor Spataru, Francisco Fernandez
(downloads: 310)
NANOPARTICLES
Mihail Iacob
(downloads: 1034)
2. SYNTHESIS OF DIFFERENT STRUCTURAL TYPES
OF ZEOLITES IN THE
HALLOYSITE-DOLOMITE-OBSIDIAN SYSTEM
Gunel Mamedova
(downloads: 725)
3. A NOVEL GREEN SYNTHESIS OF NICKEL OXIDE
NANOPARTICLES USING ARABIC GUM
Saeid Taghavi Fardood, Ali Ramazani, Sajjad Moradi
(downloads: 514)
4. ROLE OF CYCLODEXTRINS IN NEW
ANTIMYCOBACTERIAL FORMULATIONS
Veaceslav Boldescu, Fliur Macaev, Gheorghe Duca
(downloads: 445)
5. SYNTHESIS, CHARACTERIZATION AND
MOLECULAR DOCKING OF CHLORO-SUBSTITUTED
HYDROXYXANTHONE DERIVATIVES
Emmy Yuanita, Harno Dwi Pranowo, Mustofa Mustofa, Respati Tri Swasono, Jufrizal Syahri, Jumina Jumina
(downloads: 411)
6. SYNTHETIC TRANSFORMATIONS OF
ENT-KAURENOIC ACID
Olga Morarescu
(downloads: 400)
7. INVESTIGATION OF VARIOUS INFLUENCING
FACTORS OF HYDROTHERMAL SYNTHESIS OF
ANALCIME ZEOLITE
Gunel Mamedova, Gunel Nasirli
(downloads: 391)
8. STUDIES ON THE WATER SOLUBILIZATION
PROCESSES OF OENOTANNINS AND THEIR
PHYSICO-CHEMICAL PROPERTIES
Gh. Duca, T. Lupaşcu, P. Vlad, V. Kulciţki, R. Nastas
(downloads: 385)
9. ORGANOCHLORINE PESTICIDES RESIDUES IN
SOIL OF SOROCA DISTRICT, REPUBLIC OF
MOLDOVA
Elena Culighin
(downloads: 346)
10. THE NATURE OF THE Co-C BOND CLEAVAGE
PROCESSES IN METHYLCOB(II)ALAMIN AND
ADENOSYLCOB(III)ALAMIN
Tudor Spataru, Francisco Fernandez
(downloads: 310)
Inorganic and coordination chemistry
Author(s):
Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2023 Volume 18, no.1
Pages: 77-85
Masahiro Mikuriya, Shun Kawauchi, Ryoji Mitsuhashi, Motohiro Tsuboi, Makoto Handa
Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2023 Volume 18, no.1
Pages: 77-85
Full Text (PDF): Download
https://doi.org/10.19261/cjm.2023.1059
Abstract (PDF)
Graphical Abstract: A heterometal complex [RuIIRuIII(n-C3H7COO)4AuIII(CN)4]n was synthesized. The X-ray crystallography elucidated a chain molecule of alternating arrangement of Ru2(n-C3H7COO)4+ and Au(CN)4– units with cis-bridging mode. Magnetic susceptibility data showed that magnetic interaction between RuIIRuIII units (S= 3/2) is negligible small with a zero-field splitting parameter D of 60 cm–1.
Downloads: 40
Author(s):
Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2023 Volume 18, no.1
Pages: 70-76
Irina Voda
Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2023 Volume 18, no.1
Pages: 70-76
Full Text (PDF): Download
Abstract (PDF)
Graphical Abstract: The use of a pillar bridging ligand coordinating through two imidazole rings and multidentate carboxylate ligand with zinc(II) generates a bidimentional coordination polymer {[Zn3(BIBPh)3(BTC)2]∙H2O}n. It has been structurally characterised and investigated by IR and thermogravimetric methods. Each metal ion is four coordinated exhibiting a slightly distorted tetrahedral coordination.
Graphical Abstract: The use of a pillar bridging ligand coordinating through two imidazole rings and multidentate carboxylate ligand with zinc(II) generates a bidimentional coordination polymer {[Zn3(BIBPh)3(BTC)2]∙H2O}n. It has been structurally characterised and investigated by IR and thermogravimetric methods. Each metal ion is four coordinated exhibiting a slightly distorted tetrahedral coordination.
Downloads: 37
Author(s):
Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2022 Volume 17, no.2
Pages: 62-72
Dumitru Ureche, Ion Bulhac, Sergiu Shova, Paulina Bourosh
Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2022 Volume 17, no.2
Pages: 62-72
Full Text (PDF): Download
Abstract (PDF)
Graphical Abstract: Two coordinating compounds of zinc(II) (1) [Zn2(DAnH2)2(1,3-bdc)2(DMSO)4] and nickel(II) (2) [Ni(DAnH2)(1,4-bdc)(DMF)2]n were obtained based on dianilineglyoxime (DAnH2), 1,3-benzenedicarboxylic acid (1,3-bdcH2) and 1,4-benzenedicarboxylic acid (1,4-bdcH2), where DMSO is dimethylsulfoxide and DMF is dimethylformamide. The molecular and crystalline structure of reported compounds were established by infrared spectroscopy and single crystal X-ray diffraction, and for 1, additionally, the 1H and 13C NMR spectroscopy was used. According to data, the Zn(II) molecular complex is a binuclear and the Ni(II) is a 1D polymer compound.
Graphical Abstract: Two coordinating compounds of zinc(II) (1) [Zn2(DAnH2)2(1,3-bdc)2(DMSO)4] and nickel(II) (2) [Ni(DAnH2)(1,4-bdc)(DMF)2]n were obtained based on dianilineglyoxime (DAnH2), 1,3-benzenedicarboxylic acid (1,3-bdcH2) and 1,4-benzenedicarboxylic acid (1,4-bdcH2), where DMSO is dimethylsulfoxide and DMF is dimethylformamide. The molecular and crystalline structure of reported compounds were established by infrared spectroscopy and single crystal X-ray diffraction, and for 1, additionally, the 1H and 13C NMR spectroscopy was used. According to data, the Zn(II) molecular complex is a binuclear and the Ni(II) is a 1D polymer compound.
Downloads: 59
Author(s):
Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2022 Volume 17, no.2
Pages: 73-83
Ozan Süleyman Ürgüt, Aydin Tavman, Muazzez Gürgan Eser
Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2022 Volume 17, no.2
Pages: 73-83
Full Text (PDF): Download
Abstract (PDF)
Supplementary Material (PDF)
Graphical Abstract: 6-Chloro-2-ferrocenyl-1H-benzimidazole and (E)-((4-chloro-2-hydroxyphenylimino)methyl)ferrocene ligands and their Fe(III), Co(II), Cu(II), Zn(II) and Pd(II) complexes were synthesized. The structure of ligands and metal complexes has been investigated by different methods. In addition, magnetic moment, molar conductivity measurements and antibacterial activity of the ligands and the complexes were investigated.
Supplementary Material (PDF)
Graphical Abstract: 6-Chloro-2-ferrocenyl-1H-benzimidazole and (E)-((4-chloro-2-hydroxyphenylimino)methyl)ferrocene ligands and their Fe(III), Co(II), Cu(II), Zn(II) and Pd(II) complexes were synthesized. The structure of ligands and metal complexes has been investigated by different methods. In addition, magnetic moment, molar conductivity measurements and antibacterial activity of the ligands and the complexes were investigated.
Downloads: 70
Author(s):
Field: Inorganic and coordination chemistry
Type: Invited paper
Issue: 2022 Volume 17, no.1
Pages: 9-17
Grigore Timco, Robin Pritchard, George Whitehead, Richard Winpenny
Field: Inorganic and coordination chemistry
Type: Invited paper
Issue: 2022 Volume 17, no.1
Pages: 9-17
Full Text (PDF): Download
Abstract (PDF)
Graphical Abstract: Four new {Cr8} rings have been synthesized and characterized; they are all based on the classic [CrF(O2CtBu)2]8 ring 1. Three routes have been studied. The first is direct synthesis, by reacting hydrated chromium(III) fluorides with the acid; this has been used to produce [CrF(O2CEt)2]8 3. The second route uses 3 as a precursor and substitute with an incoming carboxylate. This has been used to make [CrF(O2CCCl3)2]8 4 and [CrF(O2CC6F5)2]8 5. The third route uses N-ethyl-D-glucamine (H5Etglu) as a template and produces chiral rings [Cr8F4(Etglu)(O2CtBu)15] 6. The single crystal X-ray structures of these new compounds are reported.
Graphical Abstract: Four new {Cr8} rings have been synthesized and characterized; they are all based on the classic [CrF(O2CtBu)2]8 ring 1. Three routes have been studied. The first is direct synthesis, by reacting hydrated chromium(III) fluorides with the acid; this has been used to produce [CrF(O2CEt)2]8 3. The second route uses 3 as a precursor and substitute with an incoming carboxylate. This has been used to make [CrF(O2CCCl3)2]8 4 and [CrF(O2CC6F5)2]8 5. The third route uses N-ethyl-D-glucamine (H5Etglu) as a template and produces chiral rings [Cr8F4(Etglu)(O2CtBu)15] 6. The single crystal X-ray structures of these new compounds are reported.
Downloads: 121
Author(s):
Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2021 Volume 16, no.2
Pages: 66-75
Viorina Gorinchoy, Olesea Cuzan, Silvia Melnic, Oleg Petuhov, Sergiu Shova
Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2021 Volume 16, no.2
Pages: 66-75
Full Text (PDF): Download
Abstract (PDF)
Graphical Abstract: Two new μ3-oxo trinuclear heterometallic Fe2IIICrIII complexes with furan-2-carboxylic and salicylic acids with the composition: [Fe2CrO(C4H3OCOO)6(CH3OH)3]NO3·0.5CH3OH and [Fe2CrO(C6H4(OH)COO)7(CH3OH)2]·2DMA were synthesized starting from iron(III) and chromium(III) salts mixture. The complexes structures were confirmed by elemental analysis, IR, Mössbauer spectroscopies, and X-ray analysis. The atomic absorption spectroscopy confirmed that the iron: chromium ratio is 2:1. The thermal properties of both heteronuclear complexes have been investigated in oxidizing and inert atmospheres revealing the stability of the trinuclear core up to 170 and 220°C, respectively.
Graphical Abstract: Two new μ3-oxo trinuclear heterometallic Fe2IIICrIII complexes with furan-2-carboxylic and salicylic acids with the composition: [Fe2CrO(C4H3OCOO)6(CH3OH)3]NO3·0.5CH3OH and [Fe2CrO(C6H4(OH)COO)7(CH3OH)2]·2DMA were synthesized starting from iron(III) and chromium(III) salts mixture. The complexes structures were confirmed by elemental analysis, IR, Mössbauer spectroscopies, and X-ray analysis. The atomic absorption spectroscopy confirmed that the iron: chromium ratio is 2:1. The thermal properties of both heteronuclear complexes have been investigated in oxidizing and inert atmospheres revealing the stability of the trinuclear core up to 170 and 220°C, respectively.
Downloads: 84
Author(s):
Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2021 Volume 16, no.2
Pages: 58-65
Valeriia Zozulia, Vladimir Ovchynnikov, Tetiana Slyva, Julia Rusanova, Volodymyr Amirkhanov
Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2021 Volume 16, no.2
Pages: 58-65
Full Text (PDF): Download
Graphical Abstract: The novel binuclear Zn(II) complex of general formula Zn2(L)4(CH3OH)2 where HL is N-[bis(benzylamino)phosphoryl]-2,2,2-trichloroacetamide has been synthesized from non-aqueous solution and characterized by elemental analysis, FTIR and NMR spectroscopy as well by X-ray single crystal diffraction. This complex represents the third example of binuclear complexes with this ligand within four known for today.
Downloads: 55
Author(s):
Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2020 Volume 15, no.2
Pages: 62-68
Viorina Gorinchoy
Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2020 Volume 15, no.2
Pages: 62-68
Full Text (PDF): Download
DOI: http://dx.doi.org/10.19261/cjm.2020.758
Abstract (PDF)
Graphical Abstract: A new tetra-homonuclear iron(III) cluster, [Fe4O2(Sal)4(H2O)6]·4DMA·0.75H2O, where Sal= salicylic acid and DMA= N,N-dimethylacetamide consolidated via two µ3-oxo- and four salicylate-bridges was synthesized and characterized by IR spectroscopic method as well as by single crystal X-ray diffraction analysis. The structure of the obtained tetranuclear compound consists of four FeIII atoms in a “butterfly” arrangement. The coordination sphere of each of the two central FeIII atoms is generated by two μ3-oxo-bridging atoms and four oxygen atoms provided by the tridentate-bridging Sal2- ligands, while the coordination polyhedron of another two iron atoms involve six oxygen atoms from three water molecules, two salicylic and one μ3-oxigen atom. The Fe-O distances within Fe-O-Fe bridge are of 2.102(3) Å (for wing-body) and 2.038(3) Å (for body-body).
Downloads: 109
Author(s):
Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2020 Volume 15, no.1
Pages: 67-74
Koba Amirkhanashvili, Alexandre Sobolev, Nani Zhorzholiani, Vladimer Tsitsishvili
Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2020 Volume 15, no.1
Pages: 67-74
Full Text (PDF): Download
Abstract (PDF)
Graphical Abstract: This paper reports on the synthesis and structure re-refinement of bis(lidocaine) diaquatetrathiocyanatonickelate(II). The compound with the formula (LidH)2[Ni(NCS)4(H2O)2], where Lid is (2-(diethylamino)-N-(2,6-dimethylphenyl)acetamide, crystallizes in the monoclinic space group P21/c with a= 18.3509(5), b= 7.6532(2), c= 14.9585(4) Å, β= 109.964 (2)°, V= 1974.57 (9) Å3, and Z= 2. Coordination of the Ni2+ ion with thiocyanate ions and water molecules generates slightly distorted octahedral anion [Ni(NCS)4(H2O)2]2– with N-bonded thiocyanate groups, while two protonated cations LidH+ remain in an outer coordination field.
Graphical Abstract: This paper reports on the synthesis and structure re-refinement of bis(lidocaine) diaquatetrathiocyanatonickelate(II). The compound with the formula (LidH)2[Ni(NCS)4(H2O)2], where Lid is (2-(diethylamino)-N-(2,6-dimethylphenyl)acetamide, crystallizes in the monoclinic space group P21/c with a= 18.3509(5), b= 7.6532(2), c= 14.9585(4) Å, β= 109.964 (2)°, V= 1974.57 (9) Å3, and Z= 2. Coordination of the Ni2+ ion with thiocyanate ions and water molecules generates slightly distorted octahedral anion [Ni(NCS)4(H2O)2]2– with N-bonded thiocyanate groups, while two protonated cations LidH+ remain in an outer coordination field.
Downloads: 144
Author(s):
Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2018 Volume 13, no.2
Pages: 56-62
Elena Martsinko, Inna Seifullina, Elena Chebanenko, Olha Pirozhok, Viktoriya Dyakonenko, Svitlana Shishkina
Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2018 Volume 13, no.2
Pages: 56-62
Full Text (PDF): Download
Graphical Abstract: The new complexes [Ni(phen)3][Ge(HCit)2]•2H2O (1), [Ni(phen)3][Sn(HCit)2]•3H2O (2) (where phen is 1,10-phenanthroline, H4Cit is citric acid) were obtained. The identity, composition, and thermal stability of the complexes were established by elemental analysis, thermogravimetry, and IR spectroscopy. According to the X-ray diffraction data, the bis(citrate)germanate / bis(citrate)stannate [Ge/Sn(HCit)2]2- carries out the role of the dianion while two halves of the nickel complexes with phenanthroline [Ni(Phen)3]2+ are cations.
Downloads: 137